The rubber based mat I have has 2-3 visible layers, each of a different material and different thickness. The conductive layer is underneath. If I keep the probes at about 1cm apart underneath the mat, the DMM fluctuates somewhere around 4-8 megaohm or so, depending of how much pressure you put on the probes. This bottom ans conductive layer resembles the aspect of a dense foam when looking closely, it is always black, has about 2-3mm thickness, and it is not very resilient.
Only the top layer is cut/pierce-proof. This top layer can be in two colors from all that I've seen so far, blue or green. It is the most rubbery and much thinner, only half a mm or so. It can stretch a lot (it rather stretches than pierces), and it is a very good electrical insulator. Though, being so thin, if you place a PCB on it, the PCB traces will form parasitic capacitances with the conductive layer underneath. Casual circuits won't be affected, but high impedance or low signal circuits will most certainly malfunction.
Aside from the rubber based and the PVC based mats, there is a third type of mat that is made out of silicone, indeed. Those are much smaller, thick of about 5-7mm, and usually not colored, white translucent. They are only heat resistant, not pierce resistant like the rubber mats, and they are not antistatic.
Such a silicone mat is usually meant to be put underneath a board that will be reworked with hot air, because the silicone is very good heat insulator, so if you sit the board on such a silicone mat, you may rework/reflow larger boards that otherwise would have needed a preheater underneath the board.
https://duckduckgo.com/?t=ffab&q=translucent+silicone+mat&ia=images&iax=imagesTo complete the mat types bambuzlement, the so called "silicone soldering mats" that are colored, not translucent, and with some sort of electronic board in the picture and embossed compartments on its surface, those are often PVC mats with no resilience to heat. Unless the max temperature is specified (has to be in the range of 400*C or so), they are most probably based on PVC, and they will melt instantly if you accidentally touch them with a hot soldering iron.
