If your ADCs are going into a microprocessor you might get best results by calibrating both systems over the operating temperature range and using a look up table to compute the same output for each when sensors are at the same temperature. By the way, making two sensors sit at the same temperature is not trivial, definitely not just a matter of letting them sit in the air near each other.
A lot depends on what you mean by "same". Microdegrees? Millidegrees? 5 degrees?