Even in countries that haven't had the infrastructure problems due to many years of underinvestment and technology embargos during the communist era, you cant count on the power grid delivering anything like a clean 230V RMS 50Hz sinewave on the LINE terminal of a domestic outlet, with the NEUTRAL and Protective Earth terminals at ground potential. In many countries and most locations within them, you'll get a somewhat distorted sinewave that's within 10% of that voltage *MOST* of the time, with plenty of high voltage spikes up to about 1KV. In some locations it can be *MUCH* worse. However assuming NEUTRAL is at ground potential can get you killed - you are ONE fault away from electrocution, and that fault may not even occur in your building or due to your actions. Betting your life on Neutral reliably staying anywhere near ground potential in a Romanian (or other former communist block) home, is only an order of magnitude or two less foolish than playing Russian roulette. I'd rather cross a busy road blindfolded.
If you cant afford a Cat II rated (or better) isolated differential HV probe, this is not a measurement you should even contemplate making.
Also if you are contemplating ways of working around the need for an isolated differential probe, (and assuming you are smart and careful enough to avoid your next of kin buying you a pine box), as that's a PC hosted USB scope, the odds are that a mistake would take out the PC as well as the scope pod, so unless you use a sacrificial PC with no other important programs or data on it, the consequences could have a much higher impact on your life than simply writing off a few hundred dollars of test equipment.
Assuming you've got a sacrificial laptop with a good battery (so it will run with ONLY the single cable to the scope pod plugged into it) and a wireless keyboard and mouse so you don't have to come anywhere near it once the mains supply you are proposing to test is connected, you can *probably* get away with breaking the safety rules and floating your PC scope so you can use a non-isolated HV probe, but the whole setup needs to be treated with the same respect as an exposed uninsulated live mains busbar!