Well, it depends.
If you use too little heat then you will spend a long time trying to remove the component. As a result, more heat will be put into the surrounding area and that can damage other components.
If you use too much heat, you can damage the board (specifically the glue that holds it together or holds on the pads and tracks) or scorch the surface. If you spend too long before removing the component, this can also damage nearby components.
If your airflow is too high, this can blow away components, will increase the area heated and might spread the heat to nearby components, this might not be good if nearby components are heat sensitive. Plastic shrouds on headers or processors particularly.
If your airflow is too little, you may not heat enough of the component you want to remove for all the solder to melt at once.
All this also depends on the board around the component. For example, if you have a large ground plane then that will suck heat away from the work area and you will have to adjust your heat and flow accordingly.
With practice, you should be able to mostly set your temperature high and only adjust your airflow. Then you adjust proximity and time spent heating to achieve the desired results.
I agree strongly with the idea of getting an unwanted board and practising. IMO this is your best way forward. Also, watch some youtube videos by people who do SMD rework and upload board repair videos.
You should watch for the indicators that the work gives you, like when the solder is melted on the component you are working on or when other components you are not working on also show signs of too much heat.
And always use flux. It vastly improves wetting and allows the solder to flow.
To be honest specific temperature advice might not even be helpful for you.
For some people that is number 5 heat and number 7 flow, for others it is 75% flow and 350C and so on.
You should learn your particular gun and the settings that work with the pieces you work on.