one of the big limitations of connecting PS in series or parallel is are the supply "floating". take your ohms meter and measure the input negative to the output negative and input positive to output positive. do this in both directions. if you see a complete open in all forms, its a good indication that it could be floating (or internal circuitry is preventing you from seeing continuity in the supplies off state). assuming you have one of those low volt dc-dc converters you see all over ebay. im going to assume you do not have a floating supply.
if the supply was floating, it means it has a complete galvanic disconnect between the input and output, means no metal physically touching. this is accomplished by using some sort of transformer or isolated inductor. if you did not have a floating supply, imagine what would happen if you tried connecting 2 supplies output in series, you would take one outputs positive output, and tie it to the others negative output, just like a battery, except the 2nd supplies negative output, technically is also its negative input, its the same all the way though, you would have both supplies inputs tied in parallel to the input power, so the second supplies negative rail is the also the same as the first supplies negative rail, so you basically made a short circuit. in the parallel setup, you basically have each supply providing a voltage offset from the negative rail, if you tied both positive outputs together, any slight variation in voltage would cause the higher one to back feed the lower one. this isn't awful, and could be made to work, linear regulator circuits like the lm317, lm350, lm338 often show a parallel configuration to get higher output current. they rely on each output having their own low resistance to the common tie together point so that the load doesn't try and source all its current from one supply.