OK, so assuming it was 4.5V from the PIC, that would still be be over my 2A IDS requirement with VDS at 12V... am I reading that correctly?
... however there's no figure for RDS at those values, so it's "suck it and see" essentially?
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Each curve in Figure 5 is for a different Vgs. You're applying 4.5V so we will need to visually interpolate between the 4V and 5V curves, sort of.
You're trying to conduct 2A so you go up along the Y axis to 2A; the very large scale is hard to accurate read 2A, it's right down near the bottom.
Go right until 2A intercepts the 4.5V curve (somewhere between the 4V and 5V curve) and go down to read Vds is about 700mV.
This is the process, but because you're using such a low gate voltage the MOSFET may not actually be turning fully on, then your Vds will be a higher and your Id will be smaller.
FYI - you can think of RDSon as a useful approximation of the "fully on" (also called the linear or ohmic region) region of the curve in Figure 5. The caveat is that the MOSFET is fully switched on.
https://en.wikipedia.org/wiki/MOSFET#Modes_of_operationIn your circuit the MOSFET may not be operating in this region because Vgs is so low, which means RDSon doesn't apply anyway.