The MSP430 thing makes sense. I never abuse samples, I was got out of a bit of a hole when I was a masters student, by a company (Plessey) getting me some early samples of a GPS front end and correlator. I always feel that if I do my bit to respect the service then it may well help someone somewhere down the line. The project this is for, has a loose timescale of 6 months or so, and the budget available won't quite stretch to cover everything, so samples really help. There's bugger all money around at the moment here to develop new products so it all helps. I never rely on them for vital components but, as I say, they come from DigiKey, so once the request is approved (<24 hrs usually) then they are here in a couple of working days. I just checked my last order - June 2007 (jeez, time really flies!) So as not to abuse the limit of 8, I had 6 items in my request (d'oh).
Analog Devices are definitely tightening up too. For the more interesting parts you have to email the specific team, which is probably a good way of filtering people out. You can always tell the difference between a design professional, a student and a chancer who only wants to Ebay them. I would gladly write a line or two about the application, it seems only reasonable. Analog used to do sample requests on mail-in postcards, with a line where you wrote what the app was, but the only request for info I have had from a supplier was from Microchip of all people. They are generally cheap enough that I can just put a couple on a Farnell or RS order, but some new devices looked interesting so I sent in a request. I don't think I would rely on Maxim for any commercial design now, unless it was purely a single build batch and the chips were available immediately in quantity, too many people have got burned by them EOLing stuff without notice.
Good comment about the TI web site! If I use Firefox, their interactive on-screen parts finder craps out on me after a couple of filters, so I have to resort to IE. It also breaks when it auto logs me out after a time, and sends me to a screen I cannot log in from. Stupid piece of crap, don't they ever test these?