One of the major systems I developed and support at the office is for "CoHE Inspectors". CoHE = Control of Hazardous Energies (not just electrical, but pneumatic, chemical, mechanical, etc.) We have hundreds of workers who have special training and annual re-certification to inspect employees to work on equipment to ensure that they know where all the breaker switches, cutoff valves, etc. are for each kind of equipment.
LOTO (Lock-out, Tag-out) is the method used to physically lock-out a breaker (or valve, etc.) to prevent others from re-energizing the system, AND to personally identify the person who applied the lock, and what is being done and the timeline or scheduling, etc. They even put the photo of the person on the tag to personalize it because their life is at stake here. But preventable accidents still happen where people don't apply the proper preventive measures.