The added energy needed to boil 1x10L of water, or 10x1L of water, is obviously the same.
I assume that the question asserts that both water heaters have equal power, and therefore surface area, and the water is at an identical temperature at the start. Then only changes can be made from the boiling process and the way we treat losses.
So lets assume 2 sources of heat loss: evaporation from the hot/boiling water, and heat convection into the kettle walls.
I'm not going to speculate whatever those rates exactly are. However, if we assume they scale linearily with surface area, then we can design a kettle that has an optimal trade-off ratio between radius and height. Assuming here that a larger radius will result in more evaporation losses, and higher walls will result in more convection losses with the walls. We can find optimums for both a 1L and 10L container.
The losses of evaporation is presumably going to scale with R^2, since thats the surface area of the water body on the top of the container.
The losses in the walls is presumably going to scale with 2*R*H, as thats the surface area of the walls of the kettle.
Therefore, to balance these ratios, e.g. alpha *R^2 = beta * 2*R*H, where alpha is evaporation loss coefficient and beta is the convection loss coefficient, we can see that we must solve for R and H giving alpha and beta. Since the volume of the container is also constrained by V=R^2*H, we have a system of equation(s) that can be solved.
It means that if we go from a 1L => 10L container, we can do that either by making H 10x bigger, or R 3.16x larger. Or a mix.. whichever has the more favourable coefficient..
"Solving" the problem by having 10 containers of 1L, and boiling them one at a time (with assuming 0s switching time), is not going to help much. We have a 10x larger body of water, however, we also have 10x the losses from that smaller container.
Lets assume some extreme edge cases for such case:
Assume that alpha=0 and thus we have no evaporation losses. Having 10x 1L containers means effectively we have cut up a 10x H container into sections of 1x H. The losses into the walls should be identical, and thus it should have no influence if we boil each pot sequentially. However, since the evaporation losses is zero, we ideally would want to make R -> infinity and thus H -> 0, which makes for a non-numerical solution.
Assume that beta=0, and thus we have no losses in the walls. In this case we would want to have R -> 0, and thus H -> infinity (again non-numerical case). However, since we chop our container up in 10 sections we can reason that we also have 10x the evaporation losses. (Even where R -> 0). Ratiometrically speaking, the losses in boiling 10 separate containers is 10x worse.
The practice will probably be somewhere in between.
So my bet is on a 10L pot being more efficient, as one can set a new optimal ratio between radius and height to balance the losses of its volume.