If anyone else has any other boiling / melting point suggestions between 0C and 100C, please chime in!
Virgin coconut oils melt at 24 °C (76 °F)-- the actual value is imprecise, but it will remain constant for a given batch of oil. This can be measured by a PRT, and then used as a calibration tool for other thermometers. The more accurate the calibration, the better (but the more expensive it gets). There will be a thermal plateau just as with gallium. In a hermetically sealed container (with 1 atmosphere of Argon) this melting/freezing point will be quite stable. Pretty cool-- something you can buy at your local grocery store!
Some years ago I needed something (some substance) that could provide reference temperatures - phase transitions, like a melting point - in the range 50-100 deg. C, with a resolution of 0.1 deg. C. The complication was that I had to detect the temperatures optically, from outside a heated chamber.
Highly purified synthetic waxes didn't work. The optical response curves were way too sloppy.
I ended up using temperature-sensitive liquid crystals, at 55, 75, and 90 deg. C, custom-made by Hallcrest UK (
www.lcrhallcrest.com). The transitions were sharp enough to resolve 10 mK temperature differences, well within spec. The resolution was limited by the temperature control in the application, not by the liquid crystals themselves. For various reasons, I used the raw liquid crystal, not the microencapsulated form. I've always wanted to find out just how sharp those transitions really were. Could they resolve 1 mK? Maybe.
The US patent that resulted (
https://patents.google.com/patent/US8345215B2/en) doesn't show my best data (which came later).
Getting back to the OP's application, I suggest an interchangeable thermistor, good for +/- 0.2 C or better, e.g.:
http://www.ussensor.com/products/thermistors/leaded-thermistors/interchangeable-thermistorshttps://www.ametherm.com/thermistor/precision-interchangeable-thermistorFor linearity, maybe a PT1000, e.g. Honeywell HEL-776 or -777 (Digi-Key, Mouser), measured ratiometrically. Hard to beat the performance/price of a good thermistor, though.