I have been playing around with making silicone parts with 3D printer moulds. I used some soft shore 0030 silicone and made a few parts. The process seems to work very well. My idea is to make a 3D printed negative mould and then inject silicone to make the keyboard. Finally when the part is made, i just need to very precisely cut aluminum foil in the shape of the bottom bridging contacts and stick it with adhesive.
These are not membrane switches. Membrane is where the button presses on two sheets of plastic with a 3rd sheet of plastic with holes as a spacer and the front and back sheet have conductive traces that touch.
I don't know about 3D printing a mold, but I mill molds out of renshape and then use soft silicone to make the main body.
Sticking aluminum foil will suck. Instead get on aliexpress/ebay and buy "Conductive carbon pills" that are designed for the task. You poke one down each hole in the mold and pour your liquid silicone on top. The carbon impregnated silicone "pill" sticks to the fresh silicone as you would expect.
Don't make the holes for the carbon pads blind. You will never get them out without tearing some. Make then a stepped through hole. You can then poke them out from the other side.
When I first started doing it maybe 10 or 15 years ago the hardest part was finding the carbon pills/pads. I don't know why the Chinese sellers use the word pills but it makes it hard to find them amongst medication to reduce flatulence.