Easiest solution: spend 100-200euro on something that makes hot air. I bet you will want to use more chips that are DFN/QFN/BGA in the future. Or heck even SOIC with exposed pad.
I dont use solderpaste. Just pretin pads and add flux. Make sure the pads are reasonably flat after pretinning, and that the center pad isn't bulging too much.
Harder solution: I've messed about with iron soldering for a few years though. What I usually did, is mirror the center pad on the other side of the PCB, leave the soldermask off too, and make sure to bridge both layers with many (thermal) vias. You can then reflow the chip by heating that bottomside with an iron. Pretin the pads and add flux as you would with hot air.
I didn't invent this solution, saw it many years ago on Mikeselectricstuff:
https://youtu.be/d-f-SBC0GrUThis works reasonably for larger QFN chips. But you will need something to support your PCB, and a steady hand to find the underside of the chip for 10-20 seconds.. And also plenty of heat. I have a 80W classic Weller iron, and I was usually soldering at 400C+ with leaded solder while doing this. Cheap PCBs from China usually held up fine, but shoving 250C+ through the PCB is well beyond the glass transition temperature of many PCB board materials. So for prototypes it may be OK, but its not a terrific technique.
For smaller DFN chips its becoming practically impossible. I've had to solder down a few board sensors (light, humidity, pressure, etc.) that are only 2x2 or 3x3mm.. or ESD diodes.. or standard package crystals.. or 24 pin BGA HyperRAM. All sooo much with hot air.