For synthesis/implementation, you can enable multi-threading support (up to 4 threads for certain parts of the process), but as others have said single core performance is the main thing to look for.
For simulation, multi-threading is not used. As joelby said, isim on a webpack license does restrict the simulation speed - this is for larger designs and you will have a message appear in the log saying the speed is being limited. If you want to use a webpack license, but don't want this slow down, you can always use vivado - but be careful in case Xilinx have changed parts of their IP between versions.