Simple answer is... no damage.
Of course the PIC pin will never rise to more than approximately Vdd + 0.7v (even if Tri-stated or configured as an input).
Looking at the data-sheet for the 16F628 (as an example) Section 17.0 - Electrical specifications - Absolute Maximum ratings
The output clamp current for Vo < 0 or Vo > Vdd is + 20mA .
Similarly the input clamp current for Vi < 0 or Vi > Vdd is + 20mA so your 100uA max. is safe with a 2000% margin. ((15v-5v)/100k)
(There is an overall limit of 300mA for Vss and 250mA for Vdd, so not all I/O pins can take the maximum current simultaneously.)
Jim