Here is the amazing fact: The glow is visible at a current of a mere 500 nA
500nA is still over 1,000,000,000,000 electrons per second... each one is a possible photon.
At about a 20% probability (hence the typical efficiency of LEDs!); it would be 100%, except that:
- Some electrons are shunted through impurities or defects (especially at low currents and with shitty dice)
- Some recombine (spontaneously, or more likely at impurity sites) without emission
- Many photons get stuck inside the crystal (which, remember, has quite a high index of refraction, and the photons are created in all directions)
- And a few get stuck in the package/lens, or reflect back to the die
The first one is very apparent in circuit. Very cheap dice/emitters from China contain bargain-bin or rejected parts, often due to high leakage. These defects typically behave ohmic (~ohms to Mohms), so prevent emission at low currents (the voltage isn't high enough), but are not so great that operation at rated current is severely impaired (i.e., emission might be half or worse, but you probably already guessed that from the sticker price, riiiight?).
This is why, in a series-parallel array type emitter, you can get different intensities within a given string, at low current. If the dies were good quality, all the parts in a string would light evenly, as you would expect (you'd still expect variation between series strings though).
Tim