It all depends on what your goals are. If you want to control an LED with some PWM, then it does not matter, but if you want to achieve the highest resolution, accuracy, precision, etc possible then all small details matter. Back in the '80-ies there were voltage reference generators / calibrators that used PWM techniques and achieved 20 bits or more of resolution. It's also a topic that I'm interested in because quite good results can be achieved with a low BOM cost.
First thing would be to use a better voltage reference. You can power the uC from such a voltage reference, but there is lots of stuff going on in a microcontroller, and only using the voltage reference to power the external buffer IC both lowers the current load from the reference, and reduces all the noise generated by the uC from the PWM signal.
Whether the output of an uC is "better" then a single output from a (CMOS) TTL IC depends on both the uC used, and which TTL family. Both use an P-channel fet to switch to power rails and a N-channel Fet to switch to GND, and these switches are not ideal. There will be asymmetry, and their channel resistance is also temperature dependent. With an TTL IC you can parallel up a bunch of outputs, which reduces the output impedance relative to the PWM filter used. And a TTL buffer is cheap, so why not? If you use a DIP package, you can even stack 2 or more IC's on top of each other for paralleling more channels.
Maybe better results can be achieved with a gate driver IC. These are designed to deliver high peak currents, and thus have FET's with a small channel resistance.
Another option is to make an output buffer from 2 fets yourself. That way you can balance their properties, and even hand sort them (although that's not good for a production environment). They should also be thermally coupled (or at least close to each other) so temperature effects on the channel resistance is similar for both FET's.
EDN is already mentioned, but they have more. They have a whole series of articles about PWM + Filtering to get to DC.