The datasheet says that, this IC contains only 46 transistors. How is that possible? Even a single opamp IC contains more than 10 transistors. Looking at all those voltage references, logic gates, flip-flop, current source, opamps, oscillator and diodes, I don't understand how they did this with only 46 transistors. Can you please make an explanation?
Sorry for not directly answering your question - need more coffee!

Or some experience with the chip would be nice; I haven't used it before.
But as for this one - that's an interesting question. Check out this TI application note:
Designing Switching Voltage Regulators With the TL494. They've got what they claim to be internal schematics for everything. At a quick count: 19 in the reference, 14 in the oscillator, 13 in the dead time/PWM comparator (one combined circuit), 12 per error amplifier, and I stopped counting there! Already a total of 70... Note that TI doesn't appear to make any claims of transistor count in their datasheet. Perhaps theirs is implemented differently? I'd love to see a
full internal schematic.
Also note that you don't need nearly as many transistors to implement most of these circuits if they're not "general purpose". For some very specific applications of an "op amp" in a block diagram, you could get away with as few as
two transistors. A rough comparator could simply compare against a base-emitter threshold, meaning
one transistor! For inverting configurations (where good CMRR isn't needed, as one input is permanently tied to a fixed level), five transistors (two in a differential amplifier, two in a current mirror, and one common-emitter amplifier for the output) can make quite a good op amp.