Be happy you pounded out a design and got a board built. That's an accomplishment regardless if there is an omission.
It's hard to sound positive while being critical about someone's work. I don't want you to take it wrong.
Pins absent on a schematic symbol is bad practice, it's never done professionally for obvious reasons. Nobody likes secret pins. Six are missing!
I don't know KiCAD but would not expect it to magically run traces on a component footprint. Can you show a close up of the copper at the RP2040. If the sch symbol and footprint have an issue then I would sound the alarm, let someone know- but not sure who, if anyone looks after library integrity.
Or it's a PCB CAD learning experience and time to do a Rev. B
"IOVDD 1, 10, 22, 33, 42, 49 Power supply for digital GPIOs, nominal voltage 1.8V to 3.3V"
"DVDD 23, 50 Digital core power supply, nominal voltage 1.1V. Can be connected to VREG_VOUT, or to some other board-level power supply."
RP2040 pinout pic taken from
https://www.circuitstate.com/pinouts/raspberry-pi-pico-rp2040-microcontroller-board-pinout-diagrams/Is the crystal oscillator working? XOUT have any signal? Where is its pin 1 dot, it's not flipped?
Can you confirm the crystal p/n and frequency. Sometimes that gets messed up, or the xtal physically damaged somebody dropped it and it's dead.
YXC Crystal Oscillators X322512MSB4SI 12MHz 20pF is usually 15pF caps on quite a few RP2040 designs. You can try remove them too if the osc is dead as a last guess.