Van De Graff could be dangerous... indirectly. you could hit something next to it, could be an soldering iron, boiled water heater, your friend's face etc, due to small shock you'll get. so be careful, make sure you operate it in stable surface area and enough open space for you to jump off, and remember to earth yourself before resuming your electronics project. the operation has been explained, rubber rubbing. hi-V lo-A stuff, we have it in our school lab.