Sorry, but it's not as easy to just add this or that component to your schematic. The datasheet denotes the schematic that you apparently copied, for good reason as "simplified".
You've got to understand the working principle of the current mode controller as described in the datasheet very well. Basically, the IC switches on the MOSFET until the current charging the inductor reaches a "trip value" determined by the shunt and the feedback voltage. After that, the energy stored in the inductor is (completely or partially, depending on the choice of components and operating conditions) transfered to the HV output side. The voltage across the shunt, required to trip the end of charge comparator, can be as high as 1V (as specified in the datasheet). This already indicates that that particular SMPS controller may not be the ideal choice for your application since you waste almost 10% of your input voltage across the shunt.
This won't matter that much in case of low power flyback converters or mains-powered off-line (isolated) switchers, which this series of SMPS controllers was originally intended for, but even a 20W output converter would dissipate more than 2W in the shunt which needs to be much lower resistance than your choice of ~1 Ohm. Select the shunt to drop 1V at the peak charge current that your inductor permits. In case of a 20W inverter, I'ld expect this to be somewhere between 4 and 5A, so a shunt of 0.22 Ohms may be adequate. At high, fast changing currents, circuit layout topology becomes very important, especially in case of the ground node, otherwise you will end up with instabilities.
I'ld recommend to design a real low-power converter first (1 or 2W, maybe also at a lower, safer output voltage) to familiarize yourself with the quirks of such circuits, and after that, consider approaching the higher powered varieties. Read and understand the datasheet and the design hints contained there, it provides a lot of valuable information. And follow @T3sl4co1l's hint regarding the power-up threshold voltage -- use the UC3843
