Three thoughts :-
1/ Efficiency gain is only one conversion (let's call it the inverter) as the buck simply replaces another converter, LV buck may be less efficient than HV half bridge!
2/ Convenience, when everything is grid powered it rolls over seamlessly to/from battery/pv depending on sun & charge.
3/ Economics, one inverter is probably cheaper than many buck converters meaning payback time is less
1. DC->AC->DC, could be more efficient that direct DC->DC. I would probably expect that to be the case for higher wattage systems. The distribution should be considered and dropping 1 or 2V from 240V is negligible. Dropping 1 or 2 voltages at 24VDC is rather irritating.
2. Convenience yes. A single invertor feed and a bunch of DC adapters plugged into it like it was (and is) a normal power extension is a lot easier. I'm not concerned, yet, with grid connection. I have other plans for that, but that needs to be done BTB and via the right channels, needs budgetted, financed etc. etc. etc. That system will be entirely "normal". The system we are discussing is my "shed" system. Which ultimately I want to power my garage, my lab and my office.
3. 19V 10A buck convertors, even in automotive potted form are £10 max. £20 if you want a marata branded one. A cheap, sensibly speced cheap inverter for 1kW is £300. Which depending on your luck you might regret. YMMV like most cheap products. EDIT: Going lower on teh inverter highlights it's pointless-ness for low wattages. Nobody goes really low. 500W is about the lowest. If I want 1kW peak load to match the 40A maxima I "choose", then to be save I but the 2k or 3k cheap version.
Given it's a low input/output system. I'm concerned the quiescent power to run the invertor will end up being a very non-negligible portion of the power budget. If I'm only pulling an average of 50W over 24 hours and the invertor is consuming 20W on top of that, it makes it a bit wasteful. In that circumstance, running the lower end 24/7 stuff off the DC+Buck and leave the higher power things like the monitors to the mains invertor.