Hi!
In the UK selenium metal rectifiers were used as the mains h.t. rectifier in a.c./d.c. television receivers for many years, and it was far from unknown for these things to stink the living room out for months without showing any more obvious signs of failure, and the UK's R.S.P.C.A. regularly had to deal with animal cruelty and neglect cases because owners that had pets as well as the TV never twigged that the TV was the cause of the nauseating stink, because the dud rectifier didn't drop the h.t. enough to make the fault obvious!
The R.S.P.C.A. were equally as baffled when the silicon diode rectifier came into use for TV set h.t. supplies from about 1961/1962, that caused a sudden massive reduction in these neglect/cruelty cases all in one go at the same time!
I dealt with many pieces of thermionic valve gear using these rectifiers (and dont forget many of the earlier solid–state radiograms & record–players released by UK makers had selenium diode l.t. rectifiers as well!), but I have to admit I never had to deal with an abominably stinky one – they just went high–resistance causing very low h.t. or l.t. output!
Chris Williams