PDBs are the "Program Debug Database", basically the detached symbol files that the compiler produces for debugging; some versions of the installer shipped them for scope.exe.
With that, you get all sort of nice symbols around "VPI"/"Accessory"/"TekConnect" ("TC_*"). For example, the scope.exe embeds ROMs of a number of probes (TAP1500, TPABNC, TCP0030, P7313, P7380, tdp1500, TDP0500, P7225, P7520, TCP0150, TCP0020, TPP0500, TPP1000 and a few more) for an - apparently - integrated test suite.
Then there's Accessory::initAsTekConnect which calls EepromReadConfig::EepromReadConfig and then parses the eeprom contents.
It should also be possible to find the I2C writes for the various operations and events.