From what I tried, I got good emissivity results with... 3D printed ABS.
Note that coatings may have other important properties like thermal conductivity, low outgassing, useful temperature range, durability etc.
And it's difficult to achieve all of them: typically you want a thick coating to absorb, but that will degrade the thermal conductivity, a durable coating would use a binder that would outgas a lot, etc.
3D printed ABS is bad for many of these, but it is also so much less hassle.
I guess the good absorption comes from the macro and microscopic rougness. The later might depend on the specific ABS and temperature used though.
It would be a bad match if you're trying to build a blackbody simulator, but for baffling it's convenient.
And remember that good absorption in the visible doesn't give you any clue about the performance in LWIR, especially when comparing in the couple % reflectivity.