Directly going to the ADC pin of the µC has another problem: the ADC inputs usually require a relatively low impedance drive to work well. With a higher ímpedance (e.g. 50 K range) the capacitance at the pin also has an effect. So Ideally one would have some amplifier / buffer in front. This could provide a more standard 1 M input impedance, so that a normal scope probe could be used. For the still not so high frequencies a simple OP based buffer should be OK. With a RR type powered from the same supply as the µC no extra protetion is needed between the OP and ADC - maybe a little resistance (e.g. 1 K) to avoid interference.
One would still need protection for the OP input. The main part would be some series impedance to limit the current in case of a fault. Some OPs even have sufiicient diodes for protection inside, so one could get away without extra clamping diodes.
Zener diodes can have a high and nonlinear capacitance, but it varies a lot between types.