We control ESD by bringing "everything" (persons, equipment, devices, chips) to the same potential.
This is often done by connecting everything to earth ground (since most equipment will already be grounded). But strictly speaking, it is not necessary to tie to earth ground. Any common ground should suffice.
Connecting a person to a battery terminal just means that person and that terminal will be at the same potential. That's all. The person + battery terminal might still be at a very different potential compared to lab equipment, to the floor, to sensitive devices, etc., because they are not all tied together.
So simply connecting a person to a battery terminal cannot eliminate ESD.