An exception: 120 roll film (2.25” wide, often approximated as 6 cm) can be shot as 6x4.5, 6x6, 6x7, 6x9, 6x12, or other formats, depending on the camera (approximate cm sizes).
Yes.
Back when I was into wet photography (still have 3 good enlargers sitting in storage) I got into using 120 film.
I remember quite a while ago when it was usually referred to as "2-and-a-quarter", referring to the width of 2-1/4".
But I soon caught on to the metric way of describing the different formats, which is actually easier to use.
They're all 6cm wide (across the width of the film) but differ in height, with the sizes that Tim gave above.
My favorite is 6x9, which is a little bit wider in proportion than the standard "miniature" (35mm) camera format (24x36mm).
I also shot with a bunch of old folding plate cameras using sheet-film backs. The standard size for those was 9x12 (cm), a little smaller than our standard 4" x 5" format. Extremely high resolution if shot, developed and enlarged correctly.