Getting started, I wonder if the VNA would even need calibration. I'm thinking just a couple of transitions to start with. Saw a matched set yesterday that may be a good fit.
The WR90 is fairly common but I wonder how stable it even is. Cal the VNA at the ends of the cables with SOLT, bolt the two transitions back to back and insert them in the path. Would we expect S21 to be < +/-1dB over the range of the NanoVNA?
The cutoff of the lowest order mode for WR90 is above what the Nano can produce without harmonics. At least with mine, once you get above 8G, it gets pretty bad. At 9 after cal, S21 is maybe +/-5dB? Even when using the leakage term, the floor is maybe 15dB down is all at the highest frequencies. So there's a pretty limited range that it may be able to be used. I did buy an old PNA and am working on increasing it's frequency range but still, it's limited to 9G. It's certainly much more stable and lower noise than the Nano though.
If the WR90 components are typically stable down to their cutoff, it may be fine. From what I have been reading, I suspect that some parts may have a very narrow range it can be used and it may be well outside the range of the Nano. With many parts being old surplus, finding data sheets seems to be rare.
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I have attached some data I recently collected that compares the low cost VNA with my used Agilent. One is looking at a high pass. The other looking at the floor.