While playing with the C449 capacitor (decoupling of the +5REF powering the auxiliary MCU_ADC module incl. its reference) I saw with larger capacitors, like 100n ceramic, 4u7 ceramic, 10u tant, that the 10PLC std was always larger, like 3.5-5uV (even after adjusting). With the stock 10n one it is around 1.7uV (walking 1.4-2uV).
I've tried to simulate the situation - see below. Any capacitor larger than 10n makes the voltage not "constant" (but still noisy a bit) during the SAR conversion period.
With the stock 10nF the dip is large, but inside the dip the conversion part (the second half of the conversion clock burst) is "kept at a constant level". Mind the resolution of the MCU_ADC is aprox 5mV (but perhaps 8.5bits ENOB only, imho).
So it seems one would need a fast buffer with low output impedance to get couple of stable LSBs out of it (but important one!!, not counting runup noise contribution). Another experiment could be to replace the stock 10nF X7R with a CG0 one..
The sim is a rough aproximation only as there are most probably other parasitic factors too (resonances, TC..).
PS: the MCU_ADC conv dip is aprox the same level as the spikes in my above scope shot - coming every 20ms with 10PLC..
PPS: the auxiliary MCU_ADC works together with ASIC's comparator, where the runup is organised by the asic such the residual voltage is always around the 2.5V. So the start2end of runup voltages should be centered around the mid of 5Vcc (not the half of the +5REF). So the comparator inside the ASIC might be the another source of noise.